Dr. ADENIYI ADENUGA

Dr. ADENIYI ADENUGA

READER

Email Address: adenugaa@oauife.edu.ng

Name: Dr. ADENIYI ADENUGA

Staff: Academic Staff

Rank in the department: READER

Short Bio, Academic, and Research Activities:

B.Sc. in Chemistry, Obafemi Awolowo University Ile-Ife, Nigeria
M.Sc. in Chemistry, Obafemi Awolowo University Ile-Ife, Ile-Ife, Nigeria
M.S. in Analytical Chemistry, Portland State University, Portland, OREGON State, USA
Ph.D. IN Chemistry, Oregon State University, Corvallis, Oregon State, USA
The awareness of the chemical composition of our environment is very important because crucial changes in the chemical makeup of an environment are enough to trigger outcomes that could lead to population decline and loss of biodiversity. My expertise in the area of analytical and environmental chemistry and health is being used to address various issues of environmental significance and development of new methods to solve lingering environmental pollution and environmental health problems. New analytical methods have been developed in the area of separation science for the analysis of nanomaterials-based compounds that have been found useful in some industrial applications bringing important addition to the level of the existing knowledge on the materials.
Other areas of my research is the employment of the principles of green chemistry in the processing of samples for analysis, to this end I have developed or improved on existing methods for extraction and cleanup of organic pollutants, such as phthalate esters, organochlorine pesticides and polycyclic aromatic hydrocarbon compounds from environmental and biological samples. The methods significantly reduced the volume of hazardous organic solvents utilized in the process without compromising the quality of the results.
The use of locally-sourced agricultural biochar as an alternative low-cost absorbent for dispersive solid phase extraction absorbent (d-SPE) in the clean-up steps determination of organic contaminants, such as phthalate esters, pesticides residues and polycyclic aromatic hydrocarbons (PAHs) in samples with complex matrixes, such as milk, is being exploited to obtain inexpensive material as a replacement for the conventional, but expensive, synthetic absorbents such as graphitized carbon black (GCB), octadecyl (C18) and primary secondary amine (PSA).
In the area of renewable energy, especially in the production of biodiesel, my research has proffered an alternative pathway for processing the oilseeds of non-edible oils with high free fatty acids (FFA) and our findings have led to a significant reduction in the FFAs contents of the oils without the need to go through the cumbersome and expensive after-extraction processes like degumming or dewaxing. The application of these procedures industrially will boost the potential of using non-edible oil for large-scale biodiesel production.

Office/Room Number: CH 223

Area of Specialization: ANALYTICAL/ENVIROMENTAL CHEMISTRY

Current Research Projects for Postgraduate Students:

  1. Development of an improved method for extraction of oil from non-edible oilseeds and in situ production of biodiesel from oil seeds aided by microwave irradiation.
    (ii) Studies on the evaluation of the possible health effects of human exposure to potentially toxic metals and persistent organic pollutants in occupational and public environments
    iii. Development of improved QuEChERS method with agricultural biochar as low-cost dispersive solid-phase extraction absorbent for determination of endocrine disruptors in complex sample matrix.

List of Selected Publications (with DOI Number or a Hyperlink):

  1. Sirisaksoontorn, W., Adenuga, A. A., Remcho, V. T., & Lerner, M. M. (2011). Preparation and characterization of a tetrabutylammonium graphite intercalation compound. Journal of the American Chemical Society, 133(32), 12436-12438. https://doi.org/10.1021/ja2053539
    2. Liyanage, A. U., Ikhuoria, E. U., Adenuga, A. A., Remcho, V. T., & Lerner, M. M. (2013). Synthesis and characterization of low-generation polyamidoamine (PAMAM) dendrimer–sodium montmorillonite (Na-MMT) clay nanocomposites. Inorganic Chemistry, 52(8), 4603-4610. https://doi.org/10.1021/ic400198g
    3. Adenuga, A. A., Truong, L., Tanguay, R. L., & Remcho, V. T. (2013). Preparation of water-soluble carbon nanotubes and assessment of their biological activity in embryonic zebrafish. International journal of biomedical nanoscience and nanotechnology, 3(1-2), 38-51. https://doi.org/10.1504/IJBNN.2013.054514
    4. Saltzgaber, G., Wojcik, P. M., Sharf, T., Leyden, M. R., Wardini, J. L., Heist, C. A., … & Minot, E. D. (2013). Scalable graphene field-effect sensors for specific protein detection. Nanotechnology, 24(35), 355502. DOI 10.1088/0957-4484/24/35/355502
    5. Adenuga, A. A., Wright, M. E., & Atkinson, D. B. (2016). Evaluation of the reactivity of exhaust from various biodiesel blends as a measure of possible oxidative effects: A concern for human exposure. Chemosphere, 147, 396-403. https://doi.org/10.1016/j.chemosphere.2015.12.074
    6. Aderemi, T. A., Adenuga, A. A., Oyekunle, J. A. O., & Ogunfowokan, A. O. (2017). High level leaching of heavy metals from colorful ceramic foodwares: a potential risk to human. Environmental Science and Pollution Research, 24, 17116-17126. https://doi.org/10.1007/s11356-017-9385-7
    7. Adenuga, A. A., Amos, O. D., Oyekunle, J. A. O., & Umukoro, E. H. (2019). Adsorption performance and mechanism of a low-cost biosorbent from spent seedcake of Calophyllum inophyllum in simultaneous cleanup of potentially toxic metals from industrial wastewater. Journal of Environmental Chemical Engineering, 7(5), 103317. https://doi.org/10.1016/j.jece.2019.103317
    8. Adenuga, A. A., Idowu, O. O., & Oyekunle, J. A. O. (2020). Synthesis of quality biodiesel from Calophyllum inophyllum kernels through reactive extraction method: Optimization of process parameters and characterization of the products. Renewable Energy, 145, 2530-2537. https://doi.org/10.1016/j.renene.2019.08.035
    9. Adenuga, A. A., Ayinuola, O., Adejuyigbe, E. A., & Ogunfowokan, A. O. (2020). Biomonitoring of phthalate esters in breast milk and urine samples as biomarkers for neonates’ exposure, using modified QuEChERS method with agricultural biochar as dispersive solid-phase extraction absorbent. Microchemical Journal, 152, 104277. https://doi.org/10.1016/j.microc.2019.104277
    10. Adenuga, A. A., Oyekunle, J. A. O., & Idowu, O. O. (2021). Pathway to reduce free fatty acid formation in Calophyllum inophyllum kernel oil: A renewable feedstock for biodiesel production. Journal of Cleaner Production, 316, 128222. https://doi.org/10.1016/j.jclepro.2021.128222
    11. Adenuga, A. A., Amos, O. D., Olajide, O. D., Eludoyin, A. O., & Idowu, O. O. (2022). Environmental impact and health risk assessment of potentially toxic metals emanating from different anthropogenic activities related to E-wastes. Heliyon, 8(8). https://doi.org/10.1016/j.heliyon.2022.e10296
    12. Adenuga, A. A., Ore, O. T., Amos, O. D., Onibudo, A. O., Ayinuola, O., & Oyekunle, J. A. O. (2022). Organochlorine pesticides in therapeutic teas and human health risk assessment. Food Additives & Contaminants: Part B, 15(4), 301-309. https://doi.org/10.1080/19393210.2022.2127157
    13. Ogunlusi, G. O., Amos, O. D., Olatunji, O. F., & Adenuga, A. A. (2023). Equilibrium, kinetic, and thermodynamic studies of the adsorption of anionic and cationic dyes from aqueous solution using agricultural waste biochar. Journal of the Iranian Chemical Society, 20(4), 817-830. https://doi.org/10.1007/s13738-022-02721-6
    Google Scholar and/ Scopus Link(s): https://scholar.google.com/citations?user=-mRfbscAAAAJ&hl=en